Non-metals
The characteristics and uses of different non-metals
What are non-metals?
In chemistry all materials can be grouped into two groups:
Metals and Non-metals. There are only few elements in the periodic table that
are classified as non-metals while there are over 80 metals. However, most of
the service of the earth and the atmosphere are made up of non-metals and, most
of the materials that living things are made of are non-metals. Non-metals are
important.
Characteristics of
non-metals
Here are some of the characteristics that classify a
material or element as a non-metal.
Conduction: Non-metals are not very good conductors of electricity when compared to metals. This is because the structures of atoms of the various elements differ. We already know that everything is made up out of atoms. Atoms can be broken up into smaller particles. The middle of the atom is called the nucleus. The nucleus is made up of particles called protons and neutrons. There are smaller and lighter particles called electrons that spin around the nucleus. (See the simple model of the atom below.)
When atoms are joined together, electrons can move from one
atom to another. This is how electricity is conducted through a material. The
electrons in metals can move very easily from one atom to another so they can
conduct electricity well. However, in non-metals the electrons can’t move very
easily from atom to atom so they cannot conduct electricity very easily.
Resistance to heat: Generally non-metals have a much
lower boiling point that metals. This means that you would not be able to use
them in places where they would have to withstand high temperatures.
Density: The relationship between the
mass of something and its size or volume. A bucket of bricks will weigh more
than a bucket of feathers because the bricks have a higher density than the
feathers. Non-metals will usually be less dense than metals. If you compare the
same volume of material, non-metals will usually have less mass than metals.
Brittleness: At room temperature non-metals are
either gases like oxygen or solids like carbon. In solid form non-metals are
usually a lot more brittle than metals.
Luster: The way metals reflects light.
Non-metals are usually dull with little or no luster.
Different types of non-metals
Fibreglass: Fibreglass is also called glass
fiber. Made of very thin fibers or strands of glass, fibreglass has the same
characteristics as cloth. Fibreglass can bend and flex.
Fibreglass comes in two forms: Glass wool, made by blowing melted glass into a jet of steam.
Glass
strands, made by forcing molten glass through tiny holes. This process is
called extrusion.
Fibreglass strands can be woven into a cloth called roving
or chopped into short pieces that are laid down in no particular pattern, called
chopped strand mat.
Polymers: Polymers are everywhere. Even
your DNA is a polymer. Other polymers are the proteins and starches in our
food, the wheels on a skateboard and the tires on trucks and cars. We are
surrounded by polymers. Plastics are made from polymers.
Polymers are made of tiny molecules called monomers that are bonder together in
long chains. Monomers are made of carbon (C) and hydrogen (H) atoms. Sometimes
other elements such as oxygen (O), nitrogen (N), chlorine (Cl) and fluorine (F)
are used together with these two as well. The monomer units are joined together
by covalent bonds to form polymer chains. The polymer chains are then held
together by secondary bonds which are much weaker than the covalent bonds.
There are two groups of polymers:- thermoplastics and
thermosetting plastics.
Thermoplastics: Thermoplastics are materials
that soften and melt when you heat them. In this state you can mould them into
any shape that you want. When the material is cooled, it hardens and keeps the
shape you moulded it into. You can repeat this proses of heating and cooling
and change the shape as many times as you want.
Thermosetting
plastics: In
thermosetting plastics the polymer chains join together as cross-linked chains
or networks. This type of bonding form very strong covalent bonds and all the
polymer chains are bonded together very tightly. These cross-linked bond are
formed when the polymers are heated and undergoes a chemical reaction.
Thermosetting plastics can only be heated and moulded once.
Elastomers: All plastics are polymers but not
all polymers are plastics. Elastomers are another type of polymer. Elastomers
are sometimes called rubbers but there is a slight difference between the two
materials. An elastomer is a material that will almost, but not completely,
recover its size and shape after a load has been removed. On the other hand, a
rubber is described as a material that will go back to its original shape
almost immediately after a load has been removed.
Many elastomers has cross-linked arrangements as described
in thermosetting plastics. The hardness of the elastomer increases with the
amount of cross-linking. Once the elastomer is cross-linked it cannot be
re-shaped.
When rubbers are cross-linked, it gets harder to stretch the
material because it gets harder to pull the polymer chains out of their
position.
Ceramics: Ceramics are compounds
(mixtures) of non-metal and metal elements. Ceramics are usually made by
heating the ingredients to very high temperatures after it has been shaped or
moulded into its required shape or form. The very high temperatures allow
chemical reactions to take place in the clay so that it become permanently
hard.
Ceramics can be divided into two main classes: Traditional
ceramics and advanced ceramics.
Ceramics have many properties that make them useful. They
are harder and stiffer than steel, they are more resistant to heat and
corrosion than most metals, they are less dense than many metals and the
ingredients are found inexpensively in nature.
Ingredients of ceramics. One of the oldest materials for
making ceramics is clay, of which kaolinite is the most common. The other main
ingredient of ceramics found in nature is flint and feldspar. Flint is a type
of rock and feldspar is a group of crystalline materials that are made up of
aluminium silicates, as well as potassium, calcium or sodium.
Oxide ceramics: There are two types of oxide ceramics:- Alumina and
zirconia.
Alumina
is made from a compound called aluminium oxide. You can find aluminium oxide in
nature but because of its impurities its reactions are unpredictable.
Scientists therefore use only manmade aluminium oxide so the purity can be
controlled.
Zirconia
is made of a compound called zirconium oxide. This ceramic is very tough, and
is resistant to wear and tear and corrosion. It does not conduct heat very
well. In the industry zirconia is used to make refractory bricks and tiles
because of its terrific heat resistance.
Cermets: Cermets is a mixture of
ceramics (cer) and metallic (met) materials. As cermets contains less than 20%
metal it is classified as non-metal.
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Tungsten carbide and titanium carbide cermets
are very hard, strong and wear resistant materials. They are often used to make
cutting tools and valves.
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Silicon carbide cermet is very resistant to
wear, heat and corrosion. It stay strong, even at very high temperatures.
Because of this you can use it in furnaces that get very hot.
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Nitride cermets contain a metal bonded with
nitrogen.
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Cubic boron nitride cermet is the second hardest
material that we know of (diamond being the hardest. Because it is so hard, it
is often used in cutting tools and as abrasives on grinding wheels. This
ceramic does not exist in nature and is manmade.
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Titanium nitride cermet is often used as coating
on cutting tools to improve the useful life of the tool as it is very resistant
to wear and tear.
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Silicon nitride cermet is not really affected by
high temperatures and conduct heat well. Because of this it is used in areas
where components have to withstand very high temperatures. (car engines and gas
turbines)
Glass: Glass is an amorphous
solid. It is formed when melted materials are cooled to quickly to form regular
crystal patterns. We use soda-lime glass in windows and for light bulbs, but
there are about 750 different types of glass. Different types of glass have
different uses that include window glass, glass for containers, cookware,
lightening, glass fibers and glass that has special high temperatures,
electrical and corrosion characteristics.
Normally glass contains at least 50% silica also known as
silicon oxide. Silica is called a glass former. You can, however, change the properties
of glass by adding aluminium oxide, sodium oxide, calcium oxide, barium oxide, potassium
oxide, magnesium oxide, boron oxide or lead oxide. These oxide will then be
called intermediates or modifiers.
Glass is very brittle and will shatter when bent but it has
a very high compressive strength. Glass does not conduct electricity or heat
very well.
Diamond: Diamond is the hardest substance
that we know of. Diamonds are mined from the earth but it can also be made.
(synthetic diamonds are made) Although synthetic diamonds are exactly the same
as natural diamonds they have no impurities and therefore they are more
suitable for use in industry.
Because of its properties, diamonds have many important uses
such as:
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Cutting tool materials
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Abrasives in grinding wheels for grinding hard
materials
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Sharpening the abrasives on grinding wheels
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Coating for cutting tools
Common uses of
non-metals
Uses for fibreglass:
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Electrical, sound and heat insulation
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Glass wool is useful for isolation of house
ceilings (think pink)
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Fibreglass woven cloth is used to reinforce
plastics (cars and boats)
Properties and uses
for Polymers:
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Food and drink containers
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Packaging and signs
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Exteriors of computers and monitors and
electronic products
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Medical equipment
Ø
Paints
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Pipes, toys, hard hats, safety glasses and car
parts.
Polymers have such a wide range of products because of its
many properties which includes:
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Resistance to corrosion and chemicals
o
Poor conductors of heat and electricity
o
Low density
o
Strong and light
o
Noise insulation
o
Made in lots of colours
o
Easy to manufacture
Properties and uses
for some plastics:
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Functional
and transparent:- Lenses, goggles, safety glazing, signs, laboratory
equipment.
Ø
Functional
and decorative:- Handles, knobs, cameras, battery cases and pipe fittings
Ø
Heat
resistant:- Appliances, cookware and electrical components
Ø
Chemical
resistant:- Containers for chemicals, laboratory equipment, food and drink
containers.
Ø
Electricity
resistant:- Electrical parts and
equipment, appliances
Ø
High
friction:- Tires, non-skid surfaces, soles of shoes and flooring
Ø
Low
friction:- Sliding services and artificial joints
Ø
Wear and
tear resistant:- Gears and bearings
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Mechanically
strong:- Gears, valves, fan blades and pistons
Properties and uses
for thermoplastics
Acetyls: Strong,
stiff and abrasion resistant: - machine parts like bearings, gears and pump
impellers.
Acrylics: Quite
strong and resistant to chemicals,
weather and electricity: - (Perspex and Plexiglas) Used in lenses, furniture, windows,
lighted signs, skylights and windshields.
Acrylonitrile butadiene styrene (ABS): Very stiff and resistant to chemicals, abrasion
and electricity and very slippery (low friction): - Pipes, fittings, helmets,
tool handles, car parts, luggage and appliances.
Fluorocarbons: resistant to high temperatures, the weather, chemicals,
electricity. It’s also very slippery (low friction): - non-stick coatings for
pots and pans, electrical insulation for high temperature wires and for low
friction surfaces.
Polycarbonates: Good mechanical and electrical properties and they
can be made resistant to chemicals: - safety helmets, medical apparatus, bullet
proof windows and roof sheeting.
Polyesters: Resistant to abrasion and good electrical, mechanical and
chemical properties: - Gears, rollers and parts that must support a lot of
weight.
Polyethylenes: Good mechanical and electrical properties: - bumpers on cars,
bottles, dustbins and packaging materials.
Polystyrenes: Average properties: - disposable containers and packaging, toys
and foam insulation.
Polyvinyl chloride: (PVC) water resistant, cheap, and can be
made rigid or flexible: - Rigid; signs, pipes and conduits. Flexible; wire and
cable coatings.
Properties and uses for elastomers:
Natural rubber: Long lasting and resistant to abrasion but not a lot of
resistance to sunlight, heat and oil: - Used in tires, heals of shoes and the
mounts of engines.
Synthetic rubber: More resistant to heat, petrol and
chemicals: - tires, belts, shock absorbers and seals.
Silicones: Resistant to the biggest range of temperatures but not so
strong and low resistance to wear and tear and oil: - Seals, high temperature
electrical switches and heat insulation.
Polyurethane: good strength, stiffness and hardness properties. It is also very
resistant to cutting, abrasion and tearing: - Seals, cushioning and parts of
cars.
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